The Chemistry of Manganese, Technetium and Rhenium: Pergamon Texts in Inorganic ChemistryThe Chemistry of Manganese, Technetium and Rhenium deals with the chemistry of manganese, technetium, and rhenium and covers topics ranging from the occurrence and metallurgy of all three elements to their properties and compounds. Among the compounds considered are manganese halides, cyanides, and oxides as well as carbonyls and organometallic compounds, thiocyanate complexes, and chalcogenides. This volume is divided into three sections and opens with an overview of the history and occurrence of manganese, along with its metallurgy, uses, and properties. A variety of manganese compounds are examined, including halides and cyanides, sulfides and selenides, tellurides and borates, and nitrites and nitrates. The next two sections focus on technetium and rhenium, their discovery, isolation, and general properties. Compounds of both elements are described, including hydridic compounds, cyanide and thiocyanate complexes, and oxoacids and salts. Perrhenic acid and the perrhenates are also discussed, together with chalcogenides and refractory compounds, carbonyls, and organometallic derivatives. This book will be a valuable source of information for inorganic chemists. |
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Acta Cryst action adducts allgem alloys ammonium anhydrous anion anorg aqueous solution bond bromide carbon monoxide carbonyl cation Chem Chemistry Chim chloride complexes compounds contain coordinated crystalline crystals cyanide decomposes decomposition derivatives diamagnetic dissolves electronic ethanol F. A. Cotton fluoride formed G. E. Boyd give halides halogen heating heptaoxide hydrated hydride hydrochloric acid hydrogen hydrolysed hydroxide infrared Inorg Inorganic iodide isolated kcal mole-1 ligand liquid log Pmm magnetic magnetic moment manganese dioxide manganese(II Mn2+ MnO2 MnSO4 nitric nitrogen Nucl obtained octahedral orthorhombic oxide oxygen paramagnetic pentafluoride permanganate perrhenic acid pertechnetate phosphine Phys potassium precipitated prepared presence properties pyridine R. D. Peacock reaction reacts reduction rhenium atoms rhenium dioxide rhenium trichloride rhenium trioxide room temperature salt sodium solid soluble spectra stable structure studied sulphate sulphide Table technetium tetrachloride tetragonal tetrahedral tetrahydrofuran thiocyanate trioxide W. T. Smith X-ray yellow