Encyclopedia of Reagents for Organic Synthesis, Volume 2

a,ẞ-unsaturated acetate acyl addition affords AG(E alcohols aldehydes alkenes alkyl alkynes allylic Alternate Name amines Analysis of Reagent anion aromatic aryl benzene bond bromide carbon carbonyl carbonyl compounds carboxylic acids catalyst chiral chloride CO₂Et CO₂H CO₂Me complex Copper(I corresponding CuOTf cyclization cycloaddition cyclopropanation derivatives electrophilic enolates epoxides equiv esters Et2O ether fluoride Form Supplied formation fume hood g cm³ give Grignard Grignard reagents H₂O halides Handling hydrogen Iodide JACS ketones Lewis acid lithiation lithium m-CPBA MeCN MeOH methyl mixture mmHg n-BuLi NMe2 nucleophilic oxidation Ph Ph phenyl Physical Data Precautions Preparative Methods presence react reaction reactive Reagent Purity reduction reflux regioselectivity Related Reagents salts silyl Sodium Solubility solvents stereoselective Storage substituted substrates sulfides synthesis t-Bu t-butyl TBHP temperature tion TMEDA undergo vinyl yield eq